These steps will likely vary based on the needs of your environment, but the standard ways to connect
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To create a new host object, navigate to (1) Storage > (2) Hosts and click the (3) plus sign to add a new host object.
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Populate a (1) Name, change the personality type to (2) ESXi, optionally (3) Add to protection group after hosts are created and click (4) Create.
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Click the (1) host object hyperlink that was just created.
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Click the (1) ellipses then select (2) Configure NQNs...
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Paste the NQN from your host into (1) Port NQNs and click (2) Add to add the NQN of the host to the host object.
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To create a new host group object, click the (1) plus sign on Host Groups to create a new host group.
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Populate (1) Name with an appropriate name, optionally (2) Add to protection group after hosts are created and click (3) Create.
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Click the (1) host group object hyperlink that was just created.
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To add the host objects to the host group object, click the (1) ellipses then select (2) Add...
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Select the (1) hosts to be added to the host group and click (2) Add.
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Next, create a volume to connect to the host group and present to the ESXi hosts previously configured. Navigate to (1) Storage > (2) Volumes and click the (3) plus sign under Volumes.
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Populate a (1) Name and (2) Provisioned Size; click (3) Create to finish.
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In order to add the volume to the previously configured host group, click the (1) volume name hyperlink that was just created.
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Click the (1) ellipses and select (2) Connect...
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Select the (1) Host Group object(s) to connect to and click (2) Connect.